新奥2025年精准资料完整合集

Abstract: CO2 injection into geological formations has been proven to be an effective approach for carbon storage. When dissolved in formation water, CO2 forms carbonic acid that induces mineral dissolution at pore surfaces under acidic conditions. Comprehensive understanding of geochemical interaction between carbonic acid and reservoir rocks is crucial for assessing environmental impact on geological formations. This study focuses on a tight oil sandstone reservoir. After characterizing basic petrophysical properties and mineral composition of rock samples, a series of carbonic acid corrosion experiments with both core and corresponding pure mineral samples were carried out, respectively. Dissolution solutions collected during the experiments were analyzed to examine the variations of ion concentrations in both core and pure mineral solutions. The carbonic acid–pure mineral corrosion kinetics were investigated. The correlations between carbonic acid with core and pure mineral corrosion scenarios were established from the sample mass, reaction rate, and ion concentration. The results show that after corrosion, the mass of calcite and dolomite in the rock sample decreased by 66.7% and 27.3%, respectively. When the corrosion was stabilized, the concentrations of Ca2+ and Mg2+ in the core solution were 72.9 and 74.4 mg/L, respectively, which was 40.5–41.3 times higher than that of Na+. The reaction kinetics analysis of carbonic acid–rock revealed a two-stage reaction in the pure mineral corrosion process, rapid reaction stage, and slow reaction stage, with different reaction rate constants and reaction orders for each ion. With the correlation between carbonic acid reaction with core and pure minerals, an effective and rapid evaluation method with pure minerals for the carbonic water–rock reaction is established, which costs a shorter time and is easier to investigate. This study provides a simple and faster method to evaluate the carbonic acid corrosion reaction during geological carbon storage.